A six-component metallosupramolecular pentagon via self-sorting.
نویسندگان
چکیده
The six-component pentagon P1 with its five dynamic vertices was conceived on the basis of three different orthogonal metal complex units in a 1-fold completive self-sorting of four linear ligands and two metal ions without using directional bonding.
منابع مشابه
Self-sorting of dynamic metallosupramolecular libraries (DMLs) via metal-driven selection.
"Metal-driven" selection between finite mononuclear and polymeric metallosupramolecular species can be quantitatively achieved in solution and in a crystalline state via coupled coordination/stacking interactional algorithms within dynamic metallosupramolecular libraries - DMLs.
متن کاملSelf-sorting of equilibrating metallosupramolecular DCLs via constitutional crystallization.
Zn(2+) and Pb(2+) and ligands and self-assemble in solution to generate DCLs of interexchanging metallosupramolecular subcomponents, which convert into robust species of unique stoichiometry via constitutional crystallization.
متن کاملSelf-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
A Tröger's base-derived racemic bis(1,10-phenanthroline) ligand (rac)-1 and a bis(2,2'-bipyridine) ligand with a central 1,3-diethynylbenzene unit 2 were synthesized. Each of these ligands acts as a multivalent entity for the binding of two copper(I) ions. Upon coordination to the metal ions these two ligands undergo selective self-assembly into heteroleptic dinuclear metallosupramolecular kite...
متن کاملA seven-component metallosupramolecular quadrilateral with four different orthogonal complexation vertices.
The 4-fold completive self-sorting of a ten-component library (7 dissimilar donors and 3 different acceptors) resulted in the clean self-assembly of four dynamic orthogonal complexes although ≥143 combinations are conceivable. Due to the non-interference of the complexes, each ligand of the four combinations was embedded to one side of the quadrilateral to serve as a linkage at one metal corner...
متن کاملA fully dynamic five-component triangle via self-sorting.
Clean fabrication of a five-component supramolecular triangle was elaborated via self-sorting. The robustness of the dynamic triangle against external stimuli was challenged by varying both the metal ions and their ratios. Self-sorting of five components proved to be superior to that of four components.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Chemical communications
دوره 50 81 شماره
صفحات -
تاریخ انتشار 2014